Iterative, orthogonal strategy for oligosaccharide synthesis based on the regioselective glycosylation of polyol acceptors with partially unprotected n-pentenyl-orthoesters: further evidence for reciprocal donor acceptor selectivity (RDAS) |
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| Authors: | López J Cristóbal Agocs Attila Uriel Clara Gómez Ana M Fraser-Reid Bert |
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| Institution: | Instituto de Química Orgánica General, CSIC, Juan de la Cierva 3, 28006, Madrid, Spain. clopez@iqog.csic.es |
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| Abstract: | An efficient iterative, orthogonal protocol based on the regioselective glycosyl coupling of D-mannose polyols with, partially unprotected, n-pentenyl orthoester donors permits the synthesis of linear and branched oligosaccharides with minimal protecting group tampering. |
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