| 三(2-甲基-2-苯基丙基)锡氧衍生物的合成与生物活性 |
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| 引用本文： | 张招贵,黄艳琴,邹阳,张树奎,谢庆兰. 三(2-甲基-2-苯基丙基)锡氧衍生物的合成与生物活性[J]. 高等学校化学学报, 2002, 23(3): 399-402 |
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| 作者姓名： | 张招贵 黄艳琴 邹阳 张树奎 谢庆兰 |
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| 作者单位： | 1. 南昌大学化学系, 南昌 330047;2. 南开大学元素有机化学国家重点实验室, 天津 300071 |
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| 摘 要： | 合成了17个新的三(2-甲基-2-苯基丙基)锡氧衍生物.利用IR,1H NMR及元素分析确定了化合物的组成,描述了化合物7的结构.部分化合物的生物活性测试结果表明,它们具有很好的杀螨效果,且阴离子配体对生物活性有一定影响.
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| 关 键 词： | 三(2-甲基-2-苯基丙基)锡氧衍生物 合成 晶体结构 杀螨活性 |
| 文章编号： | 0251-0790(2002)03-0399-04 |
| 收稿时间： | 2000-12-01 |
Studies on the Biological Activities and Synthesis of Tri(2-methyl-2-phenylpropyl)tinoxide Derivatives |
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| ZHANG Zhao-Gui,HUANG Yan-Qin,ZOU Yang,ZHANG Shu-Kui,XIE Qing-Lan. Studies on the Biological Activities and Synthesis of Tri(2-methyl-2-phenylpropyl)tinoxide Derivatives[J]. Chemical Research In Chinese Universities, 2002, 23(3): 399-402 |
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| Authors: | ZHANG Zhao-Gui HUANG Yan-Qin ZOU Yang ZHANG Shu-Kui XIE Qing-Lan |
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| Affiliation: | 1. Department of Chemistry, Nanchang University, Nanchang 330047, China;2. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | Seventeen tri(2-methyl-2-phenylpropyl)tinoxide derivatives were synthesized and characterized by IR, 1H NMR and elemental analysis. Compound 7 crystallizes in the triclinic space group P1 with a=1.3944(6) nm, b=1.4846(6) nm, c=1.8028(7) nm, α=77.777(7)°, β=82.425(8)°, γ=73.581(8)°, V=3.488(2) nm3, Z=4, F(000)=1612, Dc=1.509 g/cm-3. The ω/2θ scan technique was employed to collect data in the range of 1.16°<θ<25.03°. The refinement of structure for 14452 reflections was converged to final R=0.0378, wR=0.1025. The molecular structure consists of fourcoordinated tin atom in a slightly distorted tetrahedral configuration. The bioassay tests showed a high acaricidal activity of some compounds. |
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| Keywords: | Tri(2|methyl|2|phenylpropyl)tinoxide derivatives Synthesis Crystal structure Acarcidal activity |
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