Rate constants for addition of triethylsilyl radicals to spin traps |
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Authors: | R G Gasanov L V Ivanova R Kh Freidlina |
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Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The rate constants for the addition of triethylsilyl radicals to -phenyl-N-tert-butylnitrone (kadd=(11±5)·106 liter/mole·sec) and 2,4,6-tri-tert-butylnitrosobenzene (kadd= (1.5±0.3)·109 liter/mole·sec) at 20°C were determined by the EPR method.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 938–941, April, 1984. |
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