Synthesis and One-dimensional Structure of Cobalt(Ⅱ) Complex [- (NaOC2H5) CoL2]n |
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作者姓名: | LILing GUWen YANShi-ping CHENGPeng LIAODai-zheng JIANGZong-hui SHENPan-wen |
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作者单位: | DepartmentofChemistry,NankaiUniversity,Tianjin300071,P.R.China |
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基金项目: | Supported by the National Natural Science Foundation of China(No.20171026) and Tianjin Natural Science Foundation(No.013605811). |
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摘 要: | The treatment of bis (2-hydroxybenzyl)-amine (HL) with NaOH and Co ( Ⅱ )(NO)2 gives isostructural one-dimensional coordination polymers -(NaOC2H5)CoL2]n(1). The cobalt ions have an octahedral geometry and are coordinated by two erystallographicaUy independent ligands which are further linked by β-Ophenol bridged Co and Na atoms to give a one-dimentional structure.
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关 键 词: | 合成 一维结构 钴(Ⅱ)配合物 晶体结构 钠 [-(NaOC2H5)CoL2]n 双(2-羟基苯甲基)胺 X射线分析 |
收稿时间: | 2002-09-16 |
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