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Synthesis and One-dimensional Structure of Cobalt(Ⅱ) Complex [- (NaOC2H5) CoL2]n
作者姓名:LILing  GUWen  YANShi-ping  CHENGPeng  LIAODai-zheng  JIANGZong-hui  SHENPan-wen
作者单位:DepartmentofChemistry,NankaiUniversity,Tianjin300071,P.R.China
基金项目:Supported by the National Natural Science Foundation of China(No.20171026) and Tianjin Natural Science Foundation(No.013605811).
摘    要:The treatment of bis (2-hydroxybenzyl)-amine (HL) with NaOH and Co ( Ⅱ )(NO)2 gives isostructural one-dimensional coordination polymers -(NaOC2H5)CoL2]n(1). The cobalt ions have an octahedral geometry and are coordinated by two erystallographicaUy independent ligands which are further linked by β-Ophenol bridged Co and Na atoms to give a one-dimentional structure.

关 键 词:合成  一维结构  钴(Ⅱ)配合物  晶体结构    [-(NaOC2H5)CoL2]n  双(2-羟基苯甲基)胺  X射线分析
收稿时间:2002-09-16
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