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Volumetric and transport properties of binary liquid mixtures of N-methylacetamide with lactones at temperatures (303.15 to 318.15) K
Authors:Sathyanarayana Boodida  Ranjith Kumar Bachu  Murali Krishna Patwari  Satyanarayana Nallani  
Institution:aDepartment of Chemistry, Kakatiya University, Warangal 506 009, India
Abstract:The values of density (ρ), viscosity (η) and speed of sound (u) have been measured for binary liquid mixtures of γ-butyrolactone (GBL), δ-valerolactone (DVL), and ε-caprolactone (ECL) with N-methylacetamide (NMA) over the whole composition range at T = (303.15 to 318.15) K and atmospheric pressure. From these data, excess molar volume (VE), deviation in viscosity (Δη), and deviation in isentropic compressibility (Δκs), are calculated. The results are fitted to a Redlich–Kister type polynomial equation to derive binary coefficients and standard deviations.
Keywords:N-Methylacetamide  Lactones  Excess volume  Viscosity  Isentropic compressibility
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