The problem of the tautomerism of 2-iminothiazolidin-4-one and some of its derivatives |
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Authors: | N N Khovratovich I I Chizhevskaya |
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Institution: | 1. Minsk Institute of Physical Organic Chemistry AS Belorussian SSR, Lenin Belorussian State University, Minsk
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Abstract: | IR spectroscopy is used to investigate imino-amine tautomerism of 2-iminothiazoliin-4-one and 2-phenyl (p-tolyl, benzyl)imino derivatives of thiazolidin-4-one. It is shown that in the crystalline state 2-iminothiazolidin-4-one exists in the 2-imino form, while in solution (chloroform) it exists in the amino form. 2-Phenyl- and 2-p-tolylimino derivatives of thiazolidin-4-one exist in the imino form, while 2-benzyl-iminothiazolidin-4-one exist in the amino form. |
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