Encapsulating Palladium Nanoparticles Inside Mesoporous MFI Zeolite Nanocrystals for Shape‐Selective Catalysis |
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| Authors: | Tian‐Lu Cui Wen‐Yu Ke Wen‐Bei Zhang Hong‐Hui Wang Prof. Dr. Xin‐Hao Li Prof. Dr. Jie‐Sheng Chen |
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| Affiliation: | School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, P. R. China |
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| Abstract: | Pd nanoparticles were successfully encapsulated inside mesoporous silicalite‐1 nanocrystals (Pd@mnc‐S1) by a one‐pot method. The as‐synthesized Pd@mnc‐S1 with excellent stability functioned as an active and reusable heterogeneous catalyst. The unique porosity and nanostructure of silicalite‐1 crystals endowed the Pd@mnc‐S1 material general shape‐selectivity for various catalytic reactions, including selective hydrogenation, oxidation, and carbon–carbon coupling reactions. |
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| Keywords: | mesoporous materials nanocrystals palladium shape-selective catalysis zeolites |
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