Photoinduced Copper‐Catalyzed C−H Arylation at Room Temperature |
| |
| Authors: | Dr. Fanzhi Yang Julian Koeller Prof. Dr. Lutz Ackermann |
| |
| Affiliation: | 1. Institut für Organische und Biomolekulare Chemie, Georg-August-Universit?t G?ttingen, G?ttingen, Germany;2. http://www.org.chemie.uni‐goettingen.de/ackermann/;3. International Center for Advanced Studies of Energy Conversion (ICASEC), Georg-August University of G?ttingen, Germany |
| |
| Abstract: | Room‐temperature azole C?H arylations were accomplished with inexpensive copper(I) compounds by means of photoinduced catalysis. The expedient copper catalysis set the stage for site‐selective C?H arylations of non‐aromatic oxazolines under mild reaction conditions, and provides step‐economical access to the alkaloid natural products balsoxin and texamine. |
| |
| Keywords: | alkaloids C− H activation copper photocatalysis total synthesis |
|
