Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex |
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Authors: | Prof?Dr Holger Braunschweig Dr Mehmet Ali Celik Dr Rian D Dewhurst Stephanie Kachel Benedikt Wennemann |
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Institution: | 1. http://www.braunschweiggroup.de/;2. Institut für Anorganische Chemie, Julius-Maximilians-Universit?t Würzburg, Würzburg, Germany |
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Abstract: | The complete scission of the carbon–oxygen bond of carbon monoxide, while frequently observed on bulk metals and with bimetallic and cluster transition metal complexes, is unknown with monometallic systems. Reaction of a zerovalent iron bis(borylene) complex with a cyclic (alkyl)(amino)carbene revealed a highly selective intramolecular cleavage of the C?O bond of a carbonyl ligand at room temperature, leading to the formation of a highly unusual iron complex containing a base‐stabilized (bora)alkylideneborane ligand. DFT investigation of the reaction mechanism suggested that the two Lewis acidic borylene boron atoms cooperate to cleave the C?O multiple bond. |
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Keywords: | boryl complexes borylene complexes carbon monoxide small-molecule activation transition metals |
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