Porous Organic Molecular Frameworks with Extrinsic Porosity: A Platform for Carbon Storage and Separation |
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| Authors: | Dr Jian Lü Prof?Dr Rong Cao |
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| Institution: | 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian (P.R. China;2. Fujian Provincial Key Laboratory of Soil Environmental Health and Regulation, College of Resources and Environment, Fujian Agriculture and Forestry University, Fuzhou, Fujian (P.R. China |
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| Abstract: | The assembly of porous organic molecular frameworks (POMFs), which typically evidence common feasibility and compatibility, purification, and regeneration at practical conditions, remains a strategic challenge in modern materials science and is crucial for their favorable applications in biological, medical, and environmental realms. However, instructive knowledge of well‐organized POMF assembly by supramolecular interactions is, in general, ambiguous to date. Nevertheless, a significant advance in controlled POMF assembly has been recently achieved. This Minireview highlights these approaches, with a particular focus on the design of molecular constituents and assembly strategies. We also look beyond the field of solid‐state POMF materials into the assembly and recognition in solution, thus covering recent advances in POMFs based on material design and applications in carbon storage and separation. |
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| Keywords: | adsorption carbon storage hydrogen bonds supramolecular chemistry X-ray diffraction |
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