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Mild C−H/C−C Activation by Z‐Selective Cobalt Catalysis
Authors:Daniel Zell  Qingqing Bu  Dr. Milica Feldt  Prof. Dr. Lutz Ackermann
Affiliation:1. http://www.org.chemie.uni‐goettingen.de/ackermann/;2. Institut für Organische und Biomolekulare Chemie, Georg-August-Universit?t G?ttingen, G?ttingen, Germany
Abstract:Cationic cobalt complexes enable unprecedented cobalt‐catalyzed C?H/C?C functionalizations with unique selectivity features. The versatile cobalt catalyst proved broadly applicable, enabled efficient C?H/C?C cleavage at room temperature, and delivered Z‐alkenes with excellent diastereocontrol.
Keywords:C−  C cleavage  C−  H activation  cobalt  homogeneous catalysis  stereoselectivity
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