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A P−H Functionalized Al/P Frustrated Lewis Pair: Substrate Activation and Selective Hydrogen Transfer |
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| Authors: | M. Sc. Lukas Keweloh M. Sc. Hans Klöcker Prof. Dr. Ernst‐Ulrich Würthwein Prof. Dr. Werner Uhl |
| Affiliation: | 1. Institut für Anorganische und Analytische Chemie, Westf?lische Wilhelms-Universit?t Münster, Münster, Germany;2. Organisch-chemisches Institut, Westf?lische Wilhelms-Universit?t Münster, Münster, Germany |
| Abstract: | Hydroalumination of an alkynylphosphine gave an unprecedented P?H functionalized frustrated Lewis pair (FLP). The reactive P?H group does not influence the typical FLP properties, but the activation of substrates follows a new reaction pattern involving hydrogen transfer to yield unusual compounds with phosphaurea, iminophosphine, or phosphanyltriazene structural motifs. |
| Keywords: | aluminum cooperativity density functional calculations frustrated Lewis pairs insertion reactions |