| Initiation Mechanism of Polymerization of Acryl－amide by Ceric Ion／2－Benzoyl Acetanilide System |
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| 引用本文： | DONG Jian-hua, DENG Chao, QIU Kun-yuan and FENG Xin-de(Department of Chemistry,Peking University,Beijing,100871). Initiation Mechanism of Polymerization of Acryl－amide by Ceric Ion／2－Benzoyl Acetanilide System[J]. 高等学校化学研究, 1994, 0(4) |
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| 作者姓名： | DONG Jian-hua DENG Chao QIU Kun-yuan and FENG Xin-de(Department of Chemistry Peking University Beijing 100871) |
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| 作者单位： | Department of Chemistry，Peking University，Beijing，100871 |
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| 摘 要： | ＩｎｉｔｉａｔｉｏｎＭｅｃｈａｎｉｓｍｏｆＰｏｌｙｍｅｒｉｚａｔｉｏｎｏｆＡｃｒｙｌ－ａｍｉｄｅｂｙＣｅｒｉｃＩｏｎ／２－ＢｅｎｚｏｙｌＡｃｅｔａｎｉｌｉｄｅＳｙｓｔｅｍＤＯＮＧＪｉａｎ－ｈｕａ，ＤＥＮＧＣｈａｏ，ＱＩＵＫｕｎ－ｙｕａｎａｎｄＦＥＮＧ...
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Initiation Mechanism of Polymerization of Acryl-amide by Ceric Ion/2-Benzoyl Acetanilide System |
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| DONG Jian-hua, DENG Chao, QIU Kun-yuan and FENG Xin-de. Initiation Mechanism of Polymerization of Acryl-amide by Ceric Ion/2-Benzoyl Acetanilide System[J]. Chemical Research in Chinese University, 1994, 0(4) |
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| Authors: | DONG Jian-hua DENG Chao QIU Kun-yuan FENG Xin-de |
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| Abstract: | he initiation mechanism of ceric ion/2-benzoyl acetanilide system was studiedby means of FT-IR, EPR and kinetic studies which revealed that 2-benzoyl ac-etanilide acts as a very active promotor to the polymerization initiated by ceric ion.The initiation mechanism was then proposed which involved the complex formationbetween a ceric ion and a l ,3-diketone group or a carbamate group, followed by,thedecomposition of the complex to generate C-centered secondary alkyl radical and N-centered anillido radical, both of which would initiate polymerization of vinylmonomer as the end groups of the polymers formed. |
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| Keywords: | Spin trapping and EPR 2-Benzoyl acetanilide Ceric ion Acrylamidepolymerization Intermediate of redox reaction |
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