Room temperature palladium catalysed coupling of acyl chlorides with terminal alkynes |
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| Authors: | Cox Russell J Ritson Dougal J Dane Thomas A Berge John Charmant Jonathan P H Kantacha Anob |
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| Institution: | School of Chemistry, University of Bristol, Cantock's Close, Bristol, UKBS8 1TS. r.j.cox@bris.ac.uk |
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| Abstract: | Conditions are reported for the facile, high-yielding coupling of acyl chlorides with terminal alkynes in a reaction involving palladium and copper iodide; the reaction is tolerant of a wide variety of acyl chlorides and terminal alkynes and provides a convenient one-pot route to acetylenic ketones. |
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