Validity limits of the superposition principle when applied to reactions the kinetics of which is diffusion controlled |
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| Authors: | F. Baros M. Bouchy A. Bouchy J. Y. Jezequel J. C. Andre |
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| Affiliation: | (1) Grapp-Ua 328 CNRS, Ensic-Inpl, 1 Rue Grandville, BP 451, 54001 Nancy Cedex, France |
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| Abstract: | The superposition principle which is commonly used to solve the Smoluchowsky equation can be proved to be unreliable by elementary calculations applied to a particular example. But the practical kinetic consequences are small and usually hidden whithin experimental errors.
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