Rationally Designed Three-Layered Cu2S@Carbon@MoS2 Hierarchical Nanoboxes for Efficient Sodium Storage |
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Authors: | Dr. Yongjin Fang Dr. Deyan Luan Dr. Ye Chen Prof. Shuyan Gao Prof. Xiong Wen (David) Lou |
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Affiliation: | 1. School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459 Singapore;2. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, 453007 P. R. China |
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Abstract: | Hybrid materials, integrating the merits of individual components, are ideal structures for efficient sodium storage. However, the construction of hybrid structures with decent physical/electrochemical properties is still challenging. Now, the elaborate design and synthesis of hierarchical nanoboxes composed of three-layered Cu2S@carbon@MoS2 as anode materials for sodium-ion batteries is reported. Through a facile multistep template-engaged strategy, ultrathin MoS2 nanosheets are grown on nitrogen-doped carbon-coated Cu2S nanoboxes to realize the Cu2S@carbon@MoS2 configuration. The design shortens the diffusion path of electrons/Na+ ions, accommodates the volume change of electrodes during cycling, enhances the electric conductivity of the hybrids, and offers abundant active sites for sodium uptake. By virtue of these advantages, these three-layered Cu2S@carbon@MoS2 hierarchical nanoboxes show excellent electrochemical properties in terms of decent rate capability and stable cycle life. |
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Keywords: | Cu2S MoS2 Nanoboxen N-dotierter Kohlenstoff Natrium-Ionen-Batterien |
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