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A Robust Mixed-Lanthanide PolyMOF Membrane for Ratiometric Temperature Sensing |
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| Authors: | Tongtong Feng Dr. Yingxiang Ye Xiao Liu Hui Cui Dr. Zhiqiang Li Dr. Ying Zhang Dr. Bin Liang Prof. Huanrong Li Prof. Banglin Chen |
| Affiliation: | 1. Tianjin Key Laboratory of Chemical Process Safety, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130 P. R. China These authors contributed equally to this work.;2. Department of Chemistry, University of Texas at San Antonio, San Antonio, TX, 78249 USA These authors contributed equally to this work.;3. Department of Chemistry, University of Texas at San Antonio, San Antonio, TX, 78249 USA;4. Tianjin Key Laboratory of Chemical Process Safety, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130 P. R. China |
| Abstract: | Temperature sensors play a significant role in biology, chemistry, and engineering, especially those that can work accurately in a noninvasive manner. We adopted a photoinduced post-synthetic copolymerization strategy to realize a membranous ratiometric luminescent thermometer based on the emissions of two lanthanide ions. This novel mixed-lanthanide polyMOF membrane exhibits not only the integrity and temperature sensing behaviour of the Ln-MOF powder but also excellent mechanical properties, such as flexibility, elasticity, and processability. Moreover, the polyMOF membrane shows remarkable stability under harsh conditions, including high humidity, strong acid and alkali (pH 0–14), which allowed the mapping of temperature distributions in extreme circumstances. This work highlights a simple strategy for polyMOF membrane formation and pushes forward the further practical application of Ln-MOF-based luminescent thermometers in various fields and conditions. |
| Keywords: | copolymerization lanthanides membranes metal-organic frameworks ratiometric thermometers |