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Synthesis and characterization of Pd(II)–vitamin B6 complex supported on magnetic nanoparticle as an efficient and recyclable catalyst system for C–N cross coupling of amides in deep eutectic solvents
Authors:Sepideh Bagheri  Farzane Pazoki  Naghmeh Esfandiary  Mohammad Mahdi Fadaei  Akbar Heydari
Institution:Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, 14117-13116 Iran
Abstract:Vitamin B6–Pd(II) immobilized onto magnetic nanoparticles have been successfully prepared and applied for C–Xcross-coupling reactions with aryl halides in green deep eutectic solvents. The results prove that the Fe3O4@vitamin B6–Pd(II) magnetic nanoparticles show high catalyst activity and good stability. It was also revealed that this complex can be recycled up to five times without any significant loss in catalytic activity.
Keywords:C–N cross coupling  deep eutectic solvent  magnetic  nanocatalyst  vitamin B6
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