Highly Selective and Stable Zn (II)-Based Metal–Organic Frameworks for the Detections of Tetracycline Antibiotic and Acetone in Aqueous System |
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Authors: | Bin Zhu Ziao Zong Xia Zhang Dongmei Zhang Liansheng Cui Caifeng Bi Yuhua Fan |
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Institution: | 1. College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, 266100 Shandong, China;2. School of Laboratory Medicine, Youjiang Medical University for Nationalities, Baise, 533000 Guangxi, China;3. College of Chemistry and Environmental Engineering, Baise University, Baise, Guangxi, 533000 China |
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Abstract: | Tetracycline (TC) is one of the most widely used antibiotics in aquaculture, and its good water solubility makes it a major contaminant in seawater. Therefore, it is very necessary and challenging to develop an efficient detection method. In this work, two novel metal–organic frameworks Zn (bpydb)(bimmb)0.5]n ( 1 ), {Zn2(bpydb)2(bimb)]·Zn (bpydb)(bimb)]·H2O}n ( 2 ), (bimb = 1,4-bis (lmidazol) butane, H2bypdb = 4,4′-(4,4’-Bipyridine-2,6-diyl)dibenzoic acid, bimmb = 1,4-bis (imidazol-1-ylmethyl)benzene) were successfully synthesized under solvothermal conditions. Zn-MOF 1 – 2 were characterized by X-ray powder diffraction (PXRD), Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). As expected, 1 – 2 have excellent fluorescence properties, thermal stability and good structural stability in water. TC in water can be detected by fluorescence quenching with high selectivity. At the same time, the fluorescence quenching efficiency remains unchanged in the presence of other interfering antibiotics and in aqueous solutions of different pH values (pH = 3–10). The detection ability of 1 in real seawater has not changed substantially, showing considerable practical application prospects. Interestingly, 1 – 2 also efficiently detected traces of acetone in solution with detection limits of 0.07 μM (4.38 ppb) and 0.18 μM (10.85 ppb), respectively. In addition, the mechanism of fluorescence quenching is further discussed. |
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Keywords: | antibiotic fluorescent sensor highly selective and sensitive metal–organic framework |
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