Selective,iron pentacarbonyl catalyzed reduction of aryl iodides under mild conditions |
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| Institution: | 1. Tianjin Key Laboratory of Water Resources and Environment, Tianjin Normal University, Tianjin 300387, China;2. Institute and State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China;3. Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384, China;1. School of Pharmaceutical Sciences, Central South University, Changsha 410013, China;2. School of Life Sciences, Central South University, Changsha 410013, China;1. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, 8, Arbuzov str., 420088 Kazan, Russian Federation;2. Kazan Federal University, 18, Kremlevskaya str., 420008 Kazan, Russian Federation;1. Centre for Crystal Growth, Department of Physics, SSN College of Engineering, Kalavakkam, 603110 India;2. Department of Physics, Lekshmipuram College of Arts and Science, Lekshmipuram, 629802 Tamil Nadu, India;3. National Physical Laboratory, Council of Scientific and Industrial Research, Dr K. S. Krishnan Road, New Delhi 110012, India |
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| Abstract: | Potassium tetracarbonylhydridoferrate, generated in situ from Fe(CO)5/K2CO3 in methanol has been found to bring about catalytic reduction (up to 18 cycles) of aryl iodides under 1 atm carbon monoxide pressure. This reagent is specific for iodoaromatics, and tolerates the presence of several functionnal groups. |
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