Cp2Zr(C2H4)(PMe3), der erste stabile Ethylenkomplex des Zirkoniums |
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| Institution: | 1. Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari, Venice, Italy;2. Elettra – Sincrotrone Trieste, S S 14 Km 163 5 in Area Science Park, 34149 Basovizza, Trieste, Italy;1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russia;2. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St., 28, Moscow 119991, Russia;3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russia;1. Chemistry Department, The University of Jordan, Amman 11942, Jordan;2. Chemistry Department, Tafila Technical University, Tafila 66110, Jordan;3. Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany |
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| Abstract: | The complex Cp2Zr(PMe3)2 reacts with ethylene under pressure to give the first ever stable ethylene complex of zirconium, Cp2Zr(C2H4)(PMe3). Other products of this reaction are the zirconacyclopentane complex, Cp2Zr(C4H8), and polyethylene. |
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