Ligand-directed reaction products in the nickel-catalyzed electrochemical carboxylation of terminal alkynes |
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| Affiliation: | 1. Centro de Investigação de Montanha (CIMO), Instituto Politécnico de Bragança, Bragança, Portugal;2. LAQV-REQUIMTE, Department of Chemistry, University of Aveiro, Aveiro, Portugal |
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| Abstract: | The influence of a series of N and P ligands in the nickel-catalyzed electrochemical carboxylation of 1-octyne has been studied. Different carboxylic acids are obtained depending on the nature of the ancillary ligand, and results afford an example of high ligand-directed product specificity. |
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