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Palladium(O)-catalyzed carbonylation of alkenyl- and aryl- borates and boronic acids with carbon monoxide |
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| Affiliation: | 1. CarMeN Laboratory, INRA, UMR1397, Université Lyon 1, INSERM U1060, INSA-Lyon, F-69621 Villeurbanne, France;2. UMR1253 Science et Technologie du Lait et de l''Œuf, AGROCAMPUS OUEST, INRA, F-35000 Rennes, France;3. UMR1331 Toxalim, Group of Neuro-Gastroenterology and Nutrition, INRA, F-31027 Toulouse, France |
| Abstract: | Alkenyl- and aryl-borates and boronic acids react with Co under atmospheric pressure in methanol at 25°C in the presence of a catalytic amount of Pd(PPh3)4 to give the corresponding methyl carboxylates and ketones in moderate yields. |
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