SYNTHESIS AND PHOTOPHYSICAL PROPERTIES OF POLY(ARYL IMINO) CONTAINING ACRIDINE UNITS(PAIA) |
| |
Authors: | Guan-jun Chang Lin Zhang Qing-fu Wangb Xuan Luoa Run-xiong Linb a Research Center of Laser Fusion China Academy of Engineering Physics Mianyang China b Engineering Research Center of High Performance Polymer Molding Technology Ministry of Education Qingdao University of Science Technology Qingdao China |
| |
Affiliation: | a Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, China, b Engineering Research Center of High Performance Polymer and Molding Technology, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China |
| |
Abstract: | 1,4-Bis-(4-bromobenzoyl)benzene and proflavine, 3,6-diaminoacridine free base were synthesized first. Using 1,4-bis-(4-bromobenzoyl)benzene and proflavine, 3,6-diaminoacridine free base as the monomers, poly(aryl imino) containing acridine units (PAIA) was synthesized via palladium-catalyzed amination. The structure of PAIA was characterized by means of FTIR, 1H-NMR spectroscopy and elemental analysis, the results show an agreement with the proposed structure. The UV absorption and photoluminescence spectra were tested. The absorption spectrum of the PAIA was dependent on the acidity of the media. The emission and excitation spectra of the two different forms of PAIA were investigated by photoluminescence, the addition of the trifluoroacetic acid (TFA) to the solution of PAIA does not lead to a quenching effect in the photoluminescent spectra. Additionally, DSC and TG measurements show that PAIA possess high glass transition temperature (Tg > 230°C) and good thermal stability with high decomposition temperatures in nitrogen atmosphere (TD > 500°C). |
| |
Keywords: | Poly(aryl imino) Acridine unite Palladium-catalyzed amination Photoluminescence |
本文献已被 CNKI 万方数据 等数据库收录! |
| 点击此处可从《高分子科学》浏览原始摘要信息 |
|
点击此处可从《高分子科学》下载全文 |
|