| 半夹芯16电子碳硼烷化合物Me4CpCoS2C2B10H10与二茂铁炔酮的反应性 |
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| 引用本文： | 叶红德,幸泽升,胡久荣,彭化南,谢嘉霖,刘林海,燕红.半夹芯16电子碳硼烷化合物Me4CpCoS2C2B10H10与二茂铁炔酮的反应性[J].无机化学学报,2013,29(18). |
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| 作者姓名： | 叶红德 幸泽升 胡久荣 彭化南 谢嘉霖 刘林海 燕红 |
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| 作者单位： | 上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;南京大学化学化工学院, 配位化学国家重点实验室, 南京 210093;上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;上饶师范学院化学化工学院, 江西省普通高校应用有机化学重点实验室, 上饶 334001;南京大学化学化工学院, 配位化学国家重点实验室, 南京 210093 |
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| 基金项目： | 国家自然科学基金(No.21361022、21261020),江西省教育厅2014年度普通本科高校大学生创新创业教育计划项目,南京大学配位化学国家重点实验室第25批开发课题,第54批中国博士后科学基金面上基金(No.2013M541640)资助项目. |
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| 摘 要： | 邻位碳硼烷分别与正丁基锂、硫粉和Me4CpCo(CO)I2反应合成得到半夹芯16电子碳硼烷化合物Me4CpCoS2C2B10H10 (1).1与二茂铁炔酮在二氯甲烷中反应得到产物{(Me4CpCoS2C2B10H10)FcC(O)CHCCHCC(O)Fc]} (2)(Fc=二茂铁基).2是一个1:2的加成产物,2个二茂铁炔酮分子以头-尾的方式加成到分子1中的1个Co-S键上.1和2分别用红外、核磁、元素分析、质谱和单晶X-射线衍射等表征方法进行了结构表征.
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| 关 键 词： | 半夹芯 碳硼烷 二茂铁炔酮 表征 |
Reactivity of Half-Sandwich 16e Carborane Compound Me4CpCoS2C2B10H10 with Ferrocenyne Ketone |
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| YE Hong-De,XING Ze-Sheng,HU Jiu-Rong,PENG Hua-Nan,XIE Jia-Lin,LIU Lin-Hai and YAN Hong.Reactivity of Half-Sandwich 16e Carborane Compound Me4CpCoS2C2B10H10 with Ferrocenyne Ketone[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
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| Authors: | YE Hong-De XING Ze-Sheng HU Jiu-Rong PENG Hua-Nan XIE Jia-Lin LIU Lin-Hai and YAN Hong |
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| Institution: | Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China |
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| Abstract: | o-Carborane reacts with n-butyllithium, sulfur powder and Me4CpCo(CO)I2 respectively to give the half-sandwich 16e carborane compound Me4CpCoS2C2B10H10 (1). The reaction of 1 with ferrocenyne ketone in dichloro-methane leads to the product {(Me4CpCoS2C2B10H10)FcC(O)CHCCHCC(O)Fc]} (2) (Fc=ferrocenyl). 2 is a 1:2 adduct. The alkynone is twofold inserted into one Co-S bond of 2 in a head-tail mode. 1 and 2 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis. |
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| Keywords: | half-sandwich carborane ferrocenyne ketone characterization |
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