Optimization of nickel adsorption from aqueous solution by using activated carbon prepared from waste apricot by chemical activation |
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Authors: | S. Erdo?an,C. Akmil-Ba?ar,Ç . Sar?c?-Ö zdemir,G. ?ç duygu |
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Affiliation: | a Inönü University, Chemical Engineering Department, 44069 Malatya, Turkey b Inönü University, Chemistry Department, 44069 Malatya, Turkey |
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Abstract: | Waste apricot supplied by Malatya apricot plant (Turkey) was activated by using chemical activation method and K2CO3 was chosen for this purpose. Activation temperature was varied over the temperature range of 400-900 °C and N2 atmosphere was used with 10 °C/min heat rate. The maximum surface area (1214 m2/g) and micropore volume (0.355 cm3/g) were obtained at 900 °C, but activated carbon was predominantly microporous at 700 °C. The resulting activated carbons were used for removal of Ni(II) ions from aqueous solution and adsorption properties have been investigated under various conditions such as pH, activation temperature, adsorbent dosage and nickel concentration. Adsorption parameters were determined by using Langmuir model. Optimal condition was determined as; pH 5, 0.7 g/10 ml adsorbent dosage, 10 mg/l Ni(II) concentration and 60 min contact time. The results indicate that the effective uptake of Ni(II) ions was obtained by activating the carbon at 900 °C. |
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Keywords: | Activated carbon Chemical activation Waste apricot Ni(II) adsorption Langmuir |
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