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The properties of copper films deposited on polyimide by nitrogen and oxygen plasma pre-treatment
Authors:Chih-hao Yang  Shih-chin Lee  Tien-chai Lin
Affiliation:a Department of Material Science and Engineering, National Cheng Kung University, Tainan, Taiwan, ROC
b Department of Electrical Engineering, Kun Shan University of Technology, Tainan, Taiwan, ROC
Abstract:Extensive studies on the relationship between a copper thin film and its polyimide substrate show that the adhesion strength is very weak. In this work, we show how to reduce Cu film resistivity and improve the adhesion strength between Cu and polyimide. After nitrogen and oxygen plasma treatment, polyimide substrates can substantially improve the resistivity and adhesion strength deposited Cu. It is found that the lowest resistivity is 4.22 μΩ cm and the maximum adhesion strength is 72.23 MPa for a polymide substrate treated in oxygen plasma for 5 min.
Keywords:Cu film   Plasma treatment   Adhesion   XPS   Sputtering   Polyimide   Resistivity
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