(1) Institut für Physikalische Chemie, Universität Graz, A-8010 Graz, Österreich;(2) Present address: RESART-IHM AG, Mainz, BRD
Abstract:
Intrinsic viscosity and its shear dependence of polybenzyl-L-glutamat inm-cresol suggest a slightly bent -helix. Axis ratio and rotational diffusion constant of the envelopping cylinder are determined and the length of the helix calculated, which leads to the correct molecular weight. The amount of solvated and hydrodynamically immobilized water is estimated.
Herrn Prof. Dr.G. Zigeuner zum 60. Geburtstag gewidmet.