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Methenamine as an Efficient Ligand for Copper‐catalyzed Coupling of Phenols with Aryl Halides
Authors:Cunwei Qian  Qianshou Zong  Dong Fang
Affiliation:1. School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224051, China;2. School of Biological and Chemical Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
Abstract:Employing methenamine as a new supporting ligand, the copper‐catalyzed coupling reactions of aryl bromides or aryl iodides with various phenols successfully proceeded in good yields under mild conditions. A series of diaryl ethers were obtained with excellent yields in the presence of K3PO4 and copper(I) salt.
Keywords:copper catalyst  methenamine  ullmann coupling  diaryl ethers
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