Structural studies in main group chemistry : XV. Di- and tri-organotin arylsulphonates |
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| Authors: | Philip G. Harrison Robin C. Philips John A. Richards |
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| Affiliation: | Department of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD Great Britain |
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| Abstract: | An X-ray diffraction study of (2,6-dimenthylphenyl)dicyclopentadienyl-titanium has shown the two slightly staggered cyclopentadienyl ligands to be π-bonded to the titanium atom (average distance TiC 2.35 Å); the ring planes include an angle of 41.6°. The aryl ligand is σ-bonded to the titanium atom (TiC distance 2.18 Å). The short distance (2.55 Å) between Ti and one of the methyl hydrogen atoms suggests an interaction between the two atoms. |
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| Keywords: | To whom correspondence should be addressed. |
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