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The protonation and hydrogen transfer processes in alkene and alkyne derivatives of Os3 and H2Os3(CO)10 |
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| Authors: | Eric G. Bryan W.Gregory Jackson Brian F.G. Johnson John W. Kelland Jack Lewis Karl T. Schorpp |
| Affiliation: | University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW Great Britain |
| Abstract: | The complexes H3Os3(CO)9CMe, H2Os3(CO)10, H2Os3(CO)9L (L = PEt3, PPh3 or AsPh3), HOs3(CO)10CHC(H)Ph, and Os3(CO)10HC2Me undergo protonation in acid to yield [H4Os3(CO)9CMe]+ and [H4Os3(CO)10]2+, [H3Os3(CO)9L]+, [H2Os3(CO)10CHC(H)Ph]+ and [HOs3(CO)10HC2Me]+, respectively. The structure of these ions and their hydrido-ligand transfer reactions are described. |
| Keywords: | To whom correspondence should be addressed. |
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