Photoelectron spectroscopy of f-element organometallic compounds II. Tricyclopentadienyl derivatives of uranium(IV) and thorium(IV) |
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| Authors: | I Fragala E Ciliberto RD Fischer GR Sienel P Zanella |
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| Institution: | Istituto di Chimica Generale, Universita di Catania, V. le A. Doria 6, 95125 Catania Italy;Institut für Anorganische und Angewandte Chemie, Universität Hamburg, 2000 Hamburg 13 Germany;Institut für Anorganische Chemie, Universität Erlangen N?rnberg, 8520 Erlangen Germany;Laboratorio di Chimica e Tecnologia dei Radioelementi (C.N.R.), 35100 Padova Italy |
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| Abstract: | The photoelectron spectra of some cyclopentadienyI derivatives of uranium(IV) and thorium(IV), namely (C5H5)3 ThCl, (C5H5)3 UCl, (C5 H4 CH3)3 ThCl, (C5 H4 CH3)3 UCl, (C5 H4 CH3)3 UBr and (C5 H4 CH3 )3 UBH4, are reported the metal 5f ionization has been detected in all the uranium derivative spectra and a simple molecular orbital scheme qualitatively accounts for the number and position of the observed low energy bands. |
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| Keywords: | To whom all correspondence should be addressed |
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