The redox properties of organotransition-metal complexes IV. The activation of cyclic polyolefiniron tricarbonyl derivatives by one-electron oxidation |
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| Authors: | Neil G Connelly Raymond L Kelly |
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| Institution: | Department of Inorganic Chemistry, The University, Bristol, BS8 1TS Great Britain |
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| Abstract: | Cyclic polyolefiniron tricarbonyl derivatives Fe(CO)2L(CnHm)] (L = CO or phosphorus donor) and oxidising agents such as Ag+ or NO]+ in CH2Cl2 give reactive paramagnetic cations Fe(CO)2L(CnHm]+ which can abstract hydrogen from the solvent to give Fe(CO)2L(CnHm + 1)]+. |
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| Keywords: | To whom correspondence should be addressed |
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