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Palladium‐Catalyzed Suzuki‐Miyaura Type Coupling Reaction of Aryl Halides with Triphenylborane‐Pyridine
Authors:Minghua Yang  Yongbing Gu  Yan Wang  Xiyu Zhao  Guobing Yan
Affiliation:Department of Chemistry, Lishui University, Lishui, Zhejiang 323000, China
Abstract:The Suzuki‐Miyaura type coupling reaction of aryl halides with triphenylborane‐pyridine was described. The reaction can be catalyzed by Pd(OAc)2 (5 mol%) in presence of Cs2CO3 at 50°C or 80°C, and functionalized biaryls were obtained in good to excellent yields. This protocol is general and can tolerate a wide range of functional groups.
Keywords:triphenylbroane‐pyridine  Suzuki‐Miyaura coupling  aryl halides  palladium catalysts
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