Definitive evidence that the ESR spectrum observed during photolysis of Mn2(CO)10 in THF is due to octahedral high-spin (d5) manganese(II) |
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| Authors: | A Hudson MF Lappert JJ Macquitty BK Nicholson H Zainal GR Luckhurst C Zannoni SW Bratt MCR Symons |
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| Institution: | School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain;Department of Chemistry, The University, Southampton Great Britain;Department of Chemistry, The University, Leicester Great Britain |
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| Abstract: | The reassignment to a manganese(0) quartet state by C.L. Kwan and J.K. Kochi (J. Organometal. Chem., 101 (1975) C9) of the ESR spectrum obtained during photolysis of Mn2(CO)10 in THF is shown to be in error; computer simulation of the X-band spectrum and observation of the S-band spectrum confirm our previous assignment to sextet manganese(II) and chemical and IR evidence indicate the presence of Mn(CO)5]? as a counter ion. |
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| Keywords: | To whom correspondence should be addressed No reprints available |
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