Comportement électrochimique du sulfure cuivreux non stoechiométrique dans le diméthylsulfoxyde |
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| Authors: | B. Henry J.M. Lecuire J. Bessiere |
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| Affiliation: | Laboratoire de Chimie Analytique, Université de Nancy I, C.O. 140-54037 Nancy Cedex (France) |
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| Abstract: | Electrochemical reduction of Cu2?xS in dimethylsulfoxide in chloride media is described. The material undergoes an electrochemical solution reduction under certain pH and pCl conditions, reduction of the Cu(II) species in the solid leading to destruction of the crystal. The stoichiometry of séveral copper sulfides is measured. |
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