Cationic organocarbonyl palladium(II) complexes |
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Authors: | R. Uson J. Fornies F. Martinez |
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Affiliation: | Department of Inorganic Chemistry, University of Zaragoza Spain |
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Abstract: | The carbonylation under normal pressure, at 0°C, of organometallic perchlorato palladium(II) complexes in solution leads to the displacement of the perchlorato group and the formation of a series of cationic organocarbonyl palladium(II) compounds of the general formula [CO(C6F5)PdL2]ClO4, where L2 are either two tertiary phosphine groups or a nitrogen chelate, such as 2,2′-bipyridine, 1,10-phenanthroline or N,N,N′,N′-tetramethylethylenediamine. |
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