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Nitrato(triphenylphosphine) complexes of the platinum metals; Detection of triphenylphosphine oxide ligands
Authors:Peter B. Critchlow  Stephen D. Robinson
Affiliation:Department of Chemistry, King''s College, Strand, London, WC2R 2LS Great Britain
Abstract:Reactions of some platinum group metal triphenylphosphine complexes with nitric acid afford nitrato(triphenylphosphine) derivatives in good yield; the complex “Rh(NO3) (NO)2(OPPh3)2” is positively identified as [Rh(NO3)2 (NO) (PPh3)2]
Keywords:To whom correspondence should be addressed.
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