Palladium/hydrogen catalyzed alcoholysis of benzylsilanes |
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| Authors: | Colin G. Pitt Alan E. Friedman Douglas H. Rector Mansukh C. Wani |
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| Affiliation: | Chemistry and Life Sciences Division Reasearch Triangle Institute P.O. Box 12194 Research Triangle Park, North Carolina 27709 USA |
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| Abstract: | Certain benzylsilanes are converted to methoxy or ethoxysilanes and toluene when treated with methanol or ethanol in the presence of hydrogen and catalytic amounts of palladium on charcoal. The reaction is promoted by a Si-phenyl substituent and probably by a SNSi displacement mechanism. |
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