Preparation and properties of arylgold compounds. Scope and limitations of the auration reaction |
| |
Authors: | PWJ de Graaf J Boersma GJM van der Kerk |
| |
Institution: | Laboratory for Organic Chemistry, State University, Utrecht The Netherlands |
| |
Abstract: | Several ligand-free monoarylgold dichlorides (RC6H4AuCl2)2 (R = H, Me, Et, i-Pr, t-Bu, Ph) have been prepared from arenes and AuCl3; contrary to earlier reports, addition of ligands is not necessary in order to obtain thermally stable products. The auration is inhibited if the arenes contain potentially coordinating substituents. The properties and reactions of the arylgold dichlorides are discussed. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|