The reactions of aromatic compounds with bromine trifluoride (2): Octafluoronaphthalene |
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Authors: | T.W. Bastock A.E. Pedler J.C. Tatlow |
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Affiliation: | Department of Chemistry, University of Birmingham, P.O. Box 363, Birmingham B15 2TT Great Britain |
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Abstract: | The reaction of bromine trifluoride with octafluoronaphthalene has been investigated, from which was obtained decafluoro-1,2-benzocyclohexa-1,4-diene, 2-bromo-undecafluorotetralin and a mixture of dibromotetradecafluorobicylo [4,4,0] decene isomers. Dehalogenation and reduction gave decafluoro-1,2-benzocyclohexa-1,3-diene in addition to the 1,4-diene and 2-undecafluorotetralin, a similar mixture being obtained from the dibromo decene. The reactions of the dienes and bromofluorotetralin with methoxide ion have also been studied. |
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