Addition of lithium aluminium hydride to olefins catalyzed by zirconium tetrachloride: A convenient route to alkanes and 1-haloalkanes from 1-alkenes |
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| Authors: | Fumie Sato Shigemi Sato Masao Sato |
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| Affiliation: | Department of Chemical Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152 Japan |
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| Abstract: | Lithium aluminium hydride adds to olefins in the presence of zirconium tetrachloride under mild conditions. This facile reaction offers a convenient laboratory method for the hydrogenation of olefins or for the preparation of 1-haloalkanes from olefins in high yield. Unstrained internal olefins appear to be unreactive. |
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| Keywords: | To whom correspondence should be addressed. |
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