Addition of dimethylphenylphosphine at bridging vinyl,acetylene and phenylacetylide ligands in triosmium clusters |
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| Authors: | A.J. Deeming S. Hasso |
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| Affiliation: | Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ Great Britain |
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| Abstract: | PMe2Ph readily adds at carbon in the compounds HOS3 (CHCH2)(CO)10, HOS3(CCPh)(CO)10 and OS3 (CHCH)(CO)10 to give zwitterionic 1:1 adducts; the addition to the vinyl compound is reversible and further reaction leads to OS3 (CO)10 (PMe2Ph)2 with ethylene displacement. |
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| Keywords: | Author to whom correspondence should be addressed. |
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