Magnesium-butadiene addition compounds: Isolation,structural analysis and chemical reactivity |
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| Authors: | K. Fujita Y. Ohnuma H. Yasuda H. Tani |
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| Affiliation: | Department of Polymer Science, Faculty of Science, Osaka University, Toyonaka, Osaka 560 Japan |
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| Abstract: | The magnesium-butadiene 1 : 1 (1), 1 : 2 (II) and 1 : 3 addition compounds obtained by the direct metalation of butadiene with metallic magnesium were isolated. These compounds have a polymeric structure. Structural analysis of these compounds by NMR and IR methods was carried out. The process for the formation of II via I and III via II was investigated. The results of protolysis and alkylation of the above magnesium compounds corresponded well to those of crotylmagnesium compounds. |
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| Keywords: | Address correspondence to this author. |
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