Cationic hydrido-olefin complexes of ruthenium (II). The crystal structure of hydrido(1,3-butadiene)tris-(dimethylphenylphosphine)ruthenium(II) hexafluoro-phosphate |
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| Authors: | TV Ashworth Eric Singleton M Laing |
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| Institution: | National Chemical Research Laboratory, Council for Scientific and Industrial Research, Pretoria, 0001 Republic of South Africa;Chemistry Department, University of Natal, Durban 4001 Republic of South Africa |
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| Abstract: | A route to the stable hydrido-diene salts (diene)RuHL3] PF6, (diene = cycloocta-l,5-diene, hexa-l,3-diene and buta-1,3-diene, L = PMe2 Ph; diene = cycloocta-l,5-diene, L = P(OMe)3, P(OCH2)3 CMe P(OMe)Ph2 and PMePh2) has been found and the structure of RuH(C4H6)(PMe2Ph)3] PF6 has been determined by X-ray diffraction. |
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| Keywords: | To whom correspondence should be addressed |
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