The chemistry of trifluoramine oxide. VII. Photolytic Generation and electron spin resonance spectra of F2NO radicals |
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| Authors: | N. Vanderkooi J.S. Mackenzie W.B. Fox |
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| Affiliation: | Allied Chemical Corporation, Morristown, New Jersey 07960 U.S.A.;Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375 U.S.A. |
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| Abstract: | Photolysis of solid F3NO at ?196° produces the F2NO radical identified by its 9-line ESR spectrum consisting of a fluorine split 1:2:1 triplet (aF = 143.0 G), each component of which is further split by 14N into 1:1:1 triplets (aN = 94.5 G), with g = 2.0093. Trifluoramine oxide enriched with 15N provided the expected 6-line spectrum of F215NO comprised of the fluorine triplet (aF = 142.6 G) each component of which is further split by 15N into doublets (aN = 132.3 G), with g = 2.0094. The data are best interpreted in terms of a pyramidal structure for F2NO. |
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| Keywords: | Author to whom correspondence should be addressed. |
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