A novel class of aryldiazene complexes: [(PPh3)2 (CO)IrCl(HNNC6H4R-p)(CCPh)] (BF4) (R = NO2, CN,COCH3)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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A novel class of aryldiazene complexes: [(PPh3)2 (CO)IrCl(HNNC6H4R-p)(CCPh)] (BF4) (R = NO2, CN,COCH3)

Authors:	L Toniolo D Leonesi

Institution:	lstituto di Chimica Generale ed Inorganica e di Chimica Inorganica Industriale. Universitá, Padova Italy;Istituto Chimico, Universitá, Camerino Italy

Abstract:	In the reaction with phenylacetylene leading to (PPh₃)₂(CO)IrCl (HNNC₆H₄R-p)(CCPh)] (BF₄) (R  NO₂, CN, COCH₃), the vacant coordination site in (PPh₃)₂ (CO)IrCl(N₂C₆H₄ R-p)] (BF₄) plays a key role in the activation of the acetylenic CH bond. ca]To whom correspondence should be addressed.

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