The preparation and characterisation of ruthenium cyanovinylidene complexes |
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| Authors: | Brown Neil J Eckert Prisca K Fox Mark A Yufit Dmitri S Howard Judith A K Low Paul J |
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| Institution: | Department of Chemistry, Durham University, South Rd, Durham, UK DH1 3LE. |
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| Abstract: | Reactions of half-sandwich ruthenium metal acetylide complexes with 1-cyano-4-dimethylaminopyridinium salts afford complexes containing mono- or di-cyanovinylidene ligands; the procedure can be adapted to permit the simple synthesis of a cyanoacetylide complex, via the in situ deprotonation of a primary cyanovinylidene complex. |
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