Ionic Solvation in Aqueous and Nonaqueous Solutions |
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Authors: | Hitoshi Ohtaki |
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Institution: | (1) Department of Applied Chemistry, Faculty of Science and Engineering, Ritsumeikan University, Kusatsu 525-8577, Japan, JP |
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Abstract: | Summary. The history of studies on ionic solvation is briefly reviewed, and structural and dynamic properties of solvated ions in
aqueous and nonaqueous solutions are discussed. An emphasis is placed on ionic solvation in nonaqueous mixed solvents in which
preferential solvation of ions takes place. A new parameter for expressing the degree of preferential solvation of an ion
is proposed.
Received January 16, 2001. Accepted January 31, 2001 |
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Keywords: | , ,Ionic solvation, Nonaqueous solutions, Mixed solvents, Preferential solvation, Preferential solvation quotient, |
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