Suppression of radical-cationic benzene oligomerization on sulfated zirconia |
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Authors: | Alexander F. Bedilo and Alexander M. Volodin |
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Affiliation: | (1) Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia |
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Abstract: | The effect of catalyst activation conditions on transformations of benzene cation radicals on sulfated zirconia has been studied by in situ ESR spectroscopy. After the catalyst activation at 300°C there was no oligomerization of the cation radicals to biphenyl and heavier products, which is observed after catalyst calcination at 500°C. It has been suggested that the oligomerization is suppressed by the presence of strong Br?nsted sites on the surface. |
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Keywords: | Sulfated zirconia ESR cation radicals benzene biphenyl oligomerization |
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